CHAPTER NO.11 THERMOCHEMISTRY



1.        
ΔH per mole is expressed in the units of
kJ
a. oF
b. 0C
c. K
A
2.        
Which one of the following is not a state function
a. Enthalpy
b. Heat and work
c. Temperature
d. pressure
B
3.        
for solids and liquids ΔH
a. = ΔE
b. > ΔE
c. <tE
d. ΔE = 0
A
4.        
1 k cal is equal to
a. 418 x 103 J
b. 41.8 x 103 J
c. 4.18 x 103 J
d. 0.418 x 103 J
C
5.        
Standard enthalpy for one mole of a substance which exists in its natural state at 1 atm pressrure is measure at
a. 0K
b. 298 K
c. 273 K
Non of these
B
6.        
ΔH can be measured indirectly by applying
a. Avogadro’s law
b. Gas laws
c. Hess’s law
d. Faraday’s law
A
7.        
Enthalpy means
a. Disorder
b. Transition state
c. Rate constant
d. Heat content
D
8.        
No work is done at constant
a. Pressure
b. Volume
c. temperature
d. mass
B
9.        
heat capacity depends on
a. pressure
b. volume
c. composition
d. mass
D
10.    
which one of the following reaction is spontaneous
a. endothermic
b. exothermic
c. reversible
d. irreversible
B
11.    
the energy exhibited by water in a dam is
a. potential energy
b. kinetic energy
c. electric energy
d. heat energy
A
12.    
 when heat is absorbed from the surrounding, the process is
a. Reversible
b. Mechanical
c. Exothermic
d. endothermic
D
13.    
a spontaneous reaction is one, which is accompanied by
a. lowering of energy
b. increase of energy
c. lowering of volume
d. increase of volume
A
14.    
the sum of al energies of all the molecules or atoms of a substance is called its
a. specific heat
b. heat capacity
c. latent heat
d. internal energy
D
15.    
which one of the following process has ΔH positive
a. ionization energy
b. electron affinity
c. combustion
d. exothermic reactions
A
16.    
which one of the following is example of non-spontaneous change
a. aging
b. gas mixing
c. bringing water uphill
d. all of these
C
17.    
which one of the folloqing show first law of thermodynamics
a. q = ΔE  + W
b. q = ΔE  - W
c. q = - ΔE  + W
d. non of these
A
18.    
the unit of work and heat is
a. Nm
b. J
c. Nm-2 m3
d. All of these
D
19.    
Standard heat of neutralization is
a. 890 KJ/mol
b. -57.4 KJ/mol
c. -23 KJ/mol
d. Non of these
B
20.    
1 dm3 atm =
a. 101.35 J
b. 101.35 KJ
c. 100 KJ
d. 60 J
A
21.    
When one mole od ideal gas expand from 15 dm3 to 20 dm3 against constant pressure of 2 atm. The word=k done is
a. 2 atm dm3
b. 4 atm dm3
c. 5 atm dm3
d. 10 atm dm3
D
22.    
The amount of heat absorbed by 1g of a substance to raise the temperature by one degree
a. Heat capacity
b. Specific heat
c. The molar heat capacity
d. Non of these
B
23.    
The SI unit of heat capacity is
a. JK
b. J/K
c. K/J
d. JKK
B
24.    
Heat of reaction =
a. Heat of product x heat of reactant
b. Heat of reactant – heat of product
c. Heat of product – heat of reactant

C
25.    
Heat of product/heat of reactant
q =
a. nc
b. n ΔT
c. n C ΔT
d. n C / ΔT
C


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